一、个人简介
万文明,教授,博士生导师,2005年本科毕业于哈尔滨工业大学高分子材料与工程专业;2010年博士毕业于中国科学技术大学高分子化学与物理专业;2010-2014年在美国得州大学西南医学中心、南密西西比大学、罗格斯大学做博后;2014-2023年在中国石油大学(华东)和中国科学院福建物质结构研究所任教;2023年8月加入福建师范大学,建高分子资源化学课题组(Wan-Pot Group)。在Nat. Commun.、JACS、Angew. Chem.Int. Ed.、ACS Macro Lett.、Macromolecules、Polym. Chem.等杂志上发表70多篇文章;H因子24;文章被引两千多次,6篇文章单篇被引用上百次;主持国家自然科学基金项目3项,涉密项目1项,省自然科学基金项目1项,福建省工业信息化厅重点攻关项目1项,等;2010年获中科院院长优秀奖,2016年获评青岛市西海岸新区第二批高层次紧缺人才,2018年入选中科院海西研究院“海燕”青年人才计划,2020年入选福建省引进高层次人才;2022年被Polym. Chem.杂志选为Emerging Investigator;2022年被中科院选为基础原创类特聘骨干;现为国家自然科学基金多个项目的评审专家。
二、研究方向
长期从事基于高分子合成方法学的高分子资源增值和循环利用研究。发展的聚合诱导自组装(PISA)方法,被诺贝尔化学奖得主Grubbs教授列为高分子活性聚合领域六大未来方向之一;开创的巴比耶聚合方法学,被写入庆祝中华人民共和国成立70周年专辑(中国高分子合成化学的研究与发展动态);提出的聚合诱导发光(PIE)概念,是制备非共轭发光高分子的新概念,已成为近几年高分子领域的研究热点。具体研究方向包括:1)高分子资源化学循环与升级回收;2)新(逐步/链式)聚合反应方法开发;3)巴比耶聚合方法学;4)聚合诱导发光(PIE);5)聚合诱导自组装(PISA)。
三、研究成果
(一)五篇代表作
Chen, Y. J.; Wu, L. T.; Li, T. A.; Pu, M. Q.; Sun, X. L. *; Bao, H. L.; Wan, W. M. *, Ketyl Radical Anion Mediated Radical Polymerization and Anionic Ring-Opening Polymerization to Give Polymers with Low Molecular Weight Distribution. Angew. Chem. Int. Ed., 2023, 62, e202304033.
Jing, Y. N.; Li, S. S.; Su, M.; Bao, H. *; Wan, W. M. *, Barbier Hyperbranching Polymerization-Induced Emission toward Facile Fabrication of White Light-Emitting Diode and Light-Harvesting Film. J. Am. Chem. Soc., 2019, 141, 16839-16848.
Sun, X. L.; Liu, D. M.; Tian D.; Zhang X. Y.; Wu W.; Wan, W. M. *, The Introduction of the Barbier Reaction into Polymer Chemistry. Nat. Commun.2017, 8, 1210.
Wan, W. M.; Tian, D., Jing, Y. N.; Zhang, X. Y.; * Wu, W.; Ren, H.;* Bao, H. L.*, NBN-Doped Conjugated Polycyclic Aromatic Hydrocarbons as an AIEgen Class for Extremely Sensitive Detection of Explosives. Angew. Chem. Int. Ed., 2018, 57, 15510 –15516.
Wan, W. M.; Cheng, F.; Jäkle, F.*, A Borinic Acid Polymer with Fluoride Ion- and Thermo-responsive Properties that are Tunable over a Wide Temperature Range. Angew. Chem. Int. Ed.2014,53 (34), 8934-8938.
(二)近两年论文
2023年
Pu, M. Q.; Su, M.; Chen, Y. J.; Sun, X. L.; Wan, W. M. *, Compatibility of Barbier Covalent-Anionic-Radical Polymerization with Air and Divinylbenzene. Macromolecules,2023, 56, 4895-4900.
Wu, L. T.; Li, D. S.; Shi, Q. X.; Xiao, H.; Chen, Y. J.; Sun, X. L. *; Nan, H. *; Wan, W. M. *, Barbier polymerization induced emission toward stimuli-responsive aggregation-induced emission type green non-traditional intrinsic luminescence. Dyes Pigments, 2023, 219, 111554.
Chen, Y. J.; Wu, L. T.; Li, T. A.; Pu, M. Q.; Sun, X. L. *; Bao, H. L.; Wan, W. M. *, Ketyl Radical Anion Mediated Radical Polymerization and Anionic Ring-Opening Polymerization to Give Polymers with Low Molecular Weight Distribution. Angew. Chem. Int. Ed., 2023, 62, e202304033.
李 倩,黎 明,张子明,付重先,龙海容,李德山,万文明,通过巴比耶聚合诱导发光实现非传统固有发光的波长调节研究[J/OL].聊城大学学报(自然科学版). Barbier Polymerization-Induced Emission as a Versatile Approach for Tunable Non-Traditional Intrinsic Luminescence, Journal of Liaocheng University (Natural Science Edition). 36 (2023) 23-28. https://doi.org/10.19728/j.issn1672-6634.2022110006
Su, M.; Pu, M. Q.; Xiao, H.; Chen, Y. J.; Wan, W. M. *, Super-Grignard Reagents (R2Mg·LiCl) Mediated Covalent-Anionic-Radical Polymerization Capable of Low Đ and Reactive Hydrogen Compatibility. Chin. Chem. Lett., 2023, 34, 108167.
Chen, Y. J.; Pu, M. Q.; Wu, L. T.; Sun, X. L. *; Wan, W. M. *, Nucleophilic Substitution Polymerization-Induced Emission of 1,3-Dicarbonyl Compounds as a Versatile Approach for Aggregation-Induced Emission Type Non-Traditional Intrinsic Luminescence. Chin. J. Chem., 2023, 41, 1705-1712.
Chen, Y. J.; Wu, L. T.; Xiao, H.; Sun, X. L.; Wan, W. M. *, Recent Advances and Challenges in Barbier Polymerization. ChemPlusChem, 2023, 88, e202200388.
Xue, H.; Li, D. S.; Cai, H. W.; Sun, X. L. *; Wan, W. M. *, Radical Polymerization-Induced Nontraditional Intrinsic Luminescence of Triphenylmethyl Azide-Containing Polymers. Macromolecules,2023, 56, 1898-1906.
Xiao, H.; Shi, Q. X.; Su, M.; Sun, X. L. *; Bao, H. L.; Wan, W. M. *, One-Pot Synthesis of Stimuli-Responsive Fluorescent Polymers through Polymerization-Induced Emission. ACS Macro Lett., 2023, 12, 40−47.
Su, M.; Xiao, H.; Shi, Q. X.; Sheng, Y. J.; Li, D. L.; Wan, W. M. *, N,N-dimethyl-triarylmethanolation as a versatile approach for multiresponsive emission/absorption opposite materials with capability as naked-eye alcohol and C-H acidity indicator. Mater. Today Chem. 2023, 29, 101418.
Liu, B.; Chu, B.; Zhu, L. X.; Zhang, H. K. *; Yuan, W. Z. *; Zhao, Z. *; Wan, W. M. *; Zhang, X. H. *, Clusteroluminescence: A gauge of molecular interaction. Chin. Chem. Lett., 2023, 34, 107909.
2022年
Su, M.; Pu, M. Q.; Xiao, H.; Chen, Y. J.; Li, T.; Shi, Q. X.; Sheng, Y. J.; Bao, H. L.; Wan, W. M. *, Turbo-Grignard Reagent Mediated Polymerization of Styrene under Mild Conditions Capable of Low Đ and Reactive Hydrogen Compatibility. Macromolecules,2022, 55, 10422−10429.
Li, D. S.; Sheng, Y. J.; Wu, L.T.; Chen, Y. J.; Xiao, H.; Sun, X. L. *; Bao, H. L.; Wan, W. M. *, Barbier Polymerization Induced Emission of Cinnamaldehyde: A One-Pot Grignard Reaction?. Chem. Commun., 2022, 58, 13361-13364.
Sheng, Y. J.; Su, M.; Xiao, H.; Shi, Q. X.; Sun, X. L. *; Zhang, R. L. *; Bao, H. L.; Wan, W. M. *, Barbier Hyperbranching Polymerization-Induced Emission from an AB-Type Monomer. Chem. -Eur. J., 2022, 28, e202201194.
Shi, Q. X.; Xiao, H.; Sheng, Y. J.; Li, D. S.; Su M.; Sun, X. L.; Bao, H. L.; Wan, W. M. *, Barbier single-atom polymerization induced emission as a one-pot approach towards stimuli-responsive luminescent polymers. Polym. Chem., 2022, 13, 4524-4534.
Li, T.; Liu, J.; Sun, X. L. *; Wan, W. M.; Xiao, L. R.; Qian, Q. R. *, Boronic acid-containing polymeric nanomaterials via polymerization induced self-assembly as fructose sensor. Polymer, 2022, 253, 125005.
Li, T. A.; Chiou, M. F.; Li, Y. J.; Ye, C. Q.; Su, M.; Xue, M. Y.; Yuan, X. B.; Wang, C. C.; Wan, W. M.; Li, D. L. *; Bao, H. L. *, Synthesis of unsymmetrically tetrasubstituted pyrroles and studies of AIEE in pyrrolo[1,2-a]pyrimidine derivatives. Chem. Sci., 2022, 13, 5667-5673.
Li, T.; Sheng, Y. J.; Sun, X. L. *; Wan, W. M. *; Liu, Y. R.; Qian, Q. R.; Chen, Q. H., Novel NBN-Embedded Polymers and Their Application as Fluorescent Probes in Fe3+ and Cr3+ Detection. Polymers, 2022, 14, 2025.
Su, M.; Sheng, Y. J.; Chen, Y. J.; Li, T.; Shi, Q. X.; Xiao, H.; Pu, M. Q.; Bao, H. L.; Wan, W. M. *, Living Covalent-Anionic-Radical Polymerization via a Barbier Strategy. ACS Macro Lett., 2022, 11, 354−361.
Song, L.; Yu, J. K.; Fang, K. J.; Shi, F. R.; Wan, W. M. *; Hao, L. Y.; Zhao, Z. H. *; Chen, W. C. *; Xia, Y. Z., Organometallic Magnesium Complex with Aggregation Induced Emission Properties: Synthesis, Characterization, and Fluorescent Fibers Applications. ChemPhysChem, 2022, e202100888.
Xiao, H.; Li, T.; Sun, X. L. *; Wan, W. M. *; Bao, H. L.; Qian, Q. R.; Chen, Q. H., Unpredicted Concentration-Dependent Sensory Properties of Pyrene-Containing NBN-Doped Polycyclic Aromatic Hydrocarbons. Molecules, 2022, 27, 327.
Shi, Q. X.; Li, Q.; Xiao, H.; Sun, X. L.; Bao, H. L.; Wan, W. M. *, Room-temperature Barbier single-atom polymerization induced emission as a versatile approach for the utilization of monofunctional carboxylic acid resources. Polym. Chem., 2022, 13, 592-599.
四、代表性科研项目
1. 国家自然科学基金-面上项目(单官能团酰胺和酯类化合物为单体的新聚合反应研发,直接费用:65.00万元,项目起止年月:2020年01月至 2023年 12月,在研)
2. 国家自然科学基金-面上项目(基于格氏试剂镁-杂原子交换反应的新聚合反应方法研发,直接费用:54.00万元,项目起止年月:2023年01月至 2026年 12月,在研)
3. 国家自然科学基金-青年项目(单羟基硼酸聚合物的温度响应性质研究,直接费用:22.00万元,项目起止年月:2016年01月至 2018年 12月,已结题)
4. JG项目(项目名称:高XXXXXX的设计及工艺方法,项目起止年月:2022年01月至 2023年 12月,已结题)
5. 山东省自然科学基金-青年项目(一种新型智能型硼酸高分子材料的开发,直接费用:13.00万元,项目起止年月:2015年07月至 2017年 07月,已结题)
六、联系方式
电子邮箱:wanwenming@fjnu.edu.cn
办公地址:福建省福州市乌龙江中大道18号,福建师范大学旗山校区,14号楼403室。